Refinery wastewater and its treatments

According to the lessons we have learned so far, various processes involve with hydrogen consumption and would produce wastewater. Cooling water, process water and stream, storm water, and sanitary sewage water are the four types of wastewater that were introduced in lesson 10. Process water and stream is the most polluted wastewater among four since it directly contact with petroleum fraction. Storm water could also be toxic due to exposure to pollutants and spills by accident. The pollutants that found in wastewater include toxic aromatic compounds, heteroatom compounds, strong acids, dissolved gases, suspended and dissolved solids. Compare to process water and storm water, cooling water and sanitary sewage water are less toxic and need less treatment to directly send to public treatment plants.

Refinery wastewater cannot be treated in municipal wastewater treatment plants mainly due to its capacity of treating heavy toxic chemical wastewater. Most public wastewater facilities are building to treat household wastewater and wastewater from industrial. There are some heavy chemical wastewater plants, but not many of them. As we talked about refinery wastewater previously, it contains different types of heavy toxic chemical such as H2S that municipal wastewater treatment plants hardly to treat and probably will harm the plants. It is important that refinery wastewater go through primary treatment which is physical treatment to strip H2S and remove oil and solids. Refinery wastewater also needs to go through the secondary treatment which uses microorganisms to further remove organic contaminants. After these two treatments, refinery wastewater became more applicable for public treatment facilities.

References:

1. F SC 432 class website lesson 10

https://cms.psu.edu/section/content/default.asp?WCI=pgDisplay&WCU=CRSCNT&ENTRY_ID=F20C6357261A4AE2A750C141B721E8C1

2.EPA. Washington, DC (2004). “Primer for Municipal Waste water Treatment Systems.”

Click to access primer.pdf

3. The Washington State Department of Ecology, “Water Pollution Prevention Opportunities in Petroleum Refineries” Ecology Publication No.02-07-017

Click to access 0207017.pdf

 

 

 

Incapatability of Industrial Wastewater in Municipal Treatment Facilities

While similar in nature, a municipal wastewater treatment facility and an industrial wastewater treatment facility such as one located onsite in petroleum processing plants may not be able to handle mixing input streams. This would especially be the case for adding industrial wastewater to a municipal treatment outfit because they are designed for specific types of pollutants. These pollutants include food wastes, microorganisms, viruses, bacteria, certain nutrients such as Nitrogen and Phosphorous, and household organic products such as pharmaceuticals and soaps.1 Beyond these contaminants, municipal treatment also controls levels of suspended solids and biochemical oxygen demand (BOD) among other things which do exist in industrial wastewater, however the problems is there are more than just these pollutants coming from refineries. For example, BOD, Nitrogen, Phosphorous, and suspended solids are accompanied by contaminants like oils, hydrocarbons, mercaptans, phenols, toxic compounds such as cyanides and H2S or even strong acids such as sulfuric acid and hydrofluoric acid. Municipal installations are simply not built to handle these types of pollutants and would therefore either slowly destroy the municipal plant or allow the toxins to flow directly into the clean water supply. A report by the EPA said that refineries may use one to two and a half gallons of water for every gallon of product they produce3 which would lead to an enormous amount of pollutants entering our water supply.

  1. Velegol, Stephanie . “CE 370 – Module #7a: Wastewater Components.” Penn State College of Engineering . N.p., n.d. Web. 23 July 2014. http://www.engr.psu.edu/mediaportal/flvplayer.aspx?FileID=4b42d423-1a7d-4e05-accd-9
  2. Eser, Semih. “Wastewater Treatment.” F SC 432: Petroleum Processing. N.p., n.d. Web. 23 July 2014. <https://cms.psu.edu/section/content/default.asp?WCI=pgDisplay&WCU=CRSCNT&ENTRY_ID=F20C6357261A4AE2A750C141B721E8C1>
  3. “Water & Energy Efficiency by Sectors, Oil refineries.” EPA. Environmental Protection Agency, n.d. Web. 23 July 2014. <http://www.epa.gov/region9/waterinfrastructure/oilrefineries.html#water>.

Refinery Wastewater Treatment

Post your response to the blog discussing why refinery wastewater cannot be treated in municipal wastewater treatment plants.


Among the various supporting processes comes the treatment of wastewater. Refineries use a great amount of water in many different processes including desalting, distillation, cracking, and coking. As stated in Lesson 10, there are a few types of wastewater, including cooling water, process water and steam, storm water, and sanitary sewage water. Process water and steam is usually heavily polluted since it comes in direct contact with petroleum distillates. Several pollutants can be found in wastewater, such as aromatic compounds, heteroatoms like amines, phenols, and cyanides, and acids which all have the potential to harm humans or other wildlife.

It is very important that wastewater be treated prior to being sent off to a municipal wastewater treatment plant. Sour water is contaminated with solid particles that must be stripped of like sulfur in a stripping unit, and oils that must be separated by skimming the oil that floats on top of the denser water. A secondary treatment process utilizes microorganisms as biological contactors to help separate the pollutants from the wastewater. Much of this necessity stems from the implementation of the Clean Water Act of 1972 and the incorporation of National Pollutant Discharge Elimination permits (NPDE). There are multiple stages the wastewater must go through before it is suitable enough to be treated at public facilities.